在限制性定语从句中,which 和that 在指代事物时, 一般可以互换使用, 但并非在任何情况下都是这样, 以下为宜用that, 而不宜用which 的情况。

①先行词为不定代词,all,much,something,everything,anything,nothing,none,the one等,
We should do all that is useful to the people .
There's nothing that can be said about it .
Do you mean the one that was bought yesterday?
②先行词被only, any, few, little, no, just, very, one of等词修饰时.
The only thing that we could do was to wait.
That's the very word that is wrongly used.
The last place (that) we visited was the chemical works.
You can take any (=whichever) seat that is free.
I hope the little that I can will be of some help to them.
This is the only one of the best novels that was published last year.
③先行词是序数词时或被序数词修饰时.
When we talk about Wuxi, the first that comes into mind is Tai Lake.
This is the third film that has been shown in our school this term.
④先行词是最高级或被最高级修饰时.
This is the best that can be done now.
The most important thing that should be done right now is how to stop him from going on.
⑤先行词既有人又有物,用which和who都不适合,这时宜用that. 如：
The writer and his novel that you have just talked about is really well known .
The rider and his bike that had run over an old woman were held up by the police.
⑥被修饰词为数词时.
Yesterday I caught two fish and put them in a basin of water .Now you can see the two that are still alive .
⑦如果有两个从句,其中一个关系代词已用which ,另一个关系代词宜用that,以避免语言的单调或重复.
Edison built up a factory which produced things that had never been seen before.
⑧疑问词是who或which,关系代词宜用that,以避免重复.
Which is the book that you like best?
Who is the man that is standing at the gate?
⑨主句是There be 结构,修饰其主句的定语从句宜用that 作关系代词. 如：
There is still a seat in the corner that is still free.
⑩被修饰成分为表语时,或者关系代词本身是定语从句的表语时,该关系代词宜用that .
That's a good book that will help you a lot.
My home village is no longer the place ( that ) it used to be .

网友的句子中，限制性定语从句的先行词the wine为主句的表语，故定语从句宜用that引导，而不宜用which。即以上第十条所示。