There must be something the matter with him.
为什么不定代词后面可以加名词,the matter?
《韦氏高阶》:
the matter — used to ask if there is a problem or to say that there is or is not a problem
— often + with
你可以看出,the matter with sb/sth 被用作wrong with sb/sth. 即当作形容词短语使用,所以可以在there存在句中作something的定语。
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这是个英语惯用,the matter = wrong. the matter 相当于汉语的“有问题了”。