He wants to talk to you about it.
老师,为什么about it是句子的状语,不定式的状语也说得通?
句子表达要讲究逻辑,谁先谁后。
正常的思维是:先说谈话的对象,再说谈论的内容。—— 因此,先说talk to you/talk with you,然后再说about it(谈论的内容)。
如果颠倒过来说,语法不是不可以,但有悖常理。
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你的理解正确,介词短语about it作不定式to talk to you的状语
He wants to talk about it to you(错误表达)
He wants to talk about it with you(正确表达)