根据《外研社英汉多功能词典》和《牛津英语搭配词典》(英语版)等,luxurious 的比较级和最高级分别是:more luxurious 和 most luxurious;可以放在 luxurious 前面的副词有 very,extremely,positively,wonderfully, too, so;形容词 luxurious 可以作定语和表语,例如:
The house was luxurious but unpretentious. ( 张道真主编《现代英语用法词典》修订版)
He leads a luxurious life. ( 张道真主编《现代英语用法词典》修订版)